Chemical Vapor Deposition
A Course on “CHEMICAL VAPOR DEPOSITION”
( U of L Chemical Engineering)
M. Sunkara
Assistant Professor
Chemical Engineering
mahendra@louisville.edu
502-852-1558
Objectives:
· Understand the concepts involved in the deposition of thin and thick films using various Chemical Vapor Deposition (CVD) methods.
· Apply chemical kinetics (gas phase and gas-solid), thermodynamics and transport concepts to understand the chemical vapor deposition process.
· Understand the nucleation and growth aspects of the vapor grown crystalline and amorphous films
COURSE OUTLINE
Overall review of various CVD Systems and Vacuum Environments
Thermodynamic principles involved with gas phase and gas-solid systems in CVD reactors
Lab 1: Equilibrium analysis of gas phase reactions and gas-solid reactions
Chemical kinetics of gas phase and gas-solid reactions
Lab 2: Sensitivity and steady state analysis using CHEMKIN III
Lab 3: Reaction Rate Constant Evaluation Using Molecular Modeling (MSI Software)
Chemistry of plasma systems
Lab 3: Modeling of plasma gas phase chemistry using CHEMKIN III & SAMPR
Transport considerations in CVD reactors
Lab 4: Real case simulation of RFCVD (CCP & ICP) reactors (CFDRC Software)
Thin and thick films science
Stresses in Films
Single crystal surfaces and Epitaxy
Nucleation and Growth
Texturing of polycrystalline films
Role of defects during growth and on the film properties
Lab 5: Process – Morphology Experiment using Diamond CVD
Lab 6: Monte-Carlo Simulations – Multi-Scale Modeling for Growth and Etching
This course is presently being developed as part of a CAREER award from National Science Foundation.